• 电话:0531-88364464
  • 传真:0531-88564464
  • 地址:
    中国山东省济南市山大南路27号
  • 邮编:250100

导师风采

【个人简介】

   
  • 孙宏建教授,男,1962年出生,有机化学研究所博士生导师。
  • 联系电话:0531-88361350
  • E-mail: 
  •  hjsun@sdu.edu.cn
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【学习及工作经历】

  • 1979—1983 就读于山东大学化学系,获理学学士学位。
    1983—1986 就读于山东大学化学系,获理学硕士学位;导师尹敬执教授,蒋本皋教授;
    研究方向,稀土元素热化学。
    1986—1994 留校工作,先后任助教,讲师。
    1994—1999 赴联邦德国 DarmstadtUniversity of Technology 学习;师从 Hans-Friedrich Klein 教授;研究方向,金属有机化学;获工学博士学位。
    1999—2002 德国Philipps-University of Marburg ,博士后;导师, JoergSundermeyer 教授;研究方向: 均相催化,绿色化学。
    2002 年起,作为引进人才受聘于山东大学执教。
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【主讲课程】

  • 催化化学,金属有机化学,有机合成,绿色化学导论。

     
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【研究领域和兴趣】

  • 研究方向:均相催化,绿色化学,有机合成,金属有机化学

    1、过渡金属的金属有机化学 
     作为无机化学和有机化学之间的桥梁,金属有机化学在过去的几十年中获得了飞速的发展。这主要是由于一方面金属有机化合物的合成技术,理论的不断完善及对化学学科的其它领域,如材料化学,分子生物学等的推动作用;另一方面各种过渡金属有机化合物对众多化学反应的催化作用,从聚合物的合成到新型药物的制备等都离不开金属有机化合物。我们课题小组主要进行镍,钴,铁,铂,钯等过渡金属有机化合物的设计,表征和性能研究。尤其关注以三甲基膦为辅助配体的酰基化合物和碳 - 碳偶联反应的研究。同时探索相关的反应机理。
    2、均相催化 
    众所周知,在工业化学和有机合成中大多数反应都是在催化剂的作用下获得高产率和优良的选择性。我们利用所合成的金属有机化合物对有机反应进行催化作用研究。重点研究(空气)氧化反应和脱卤反应。
    3、绿色化学 
    随着人类对环境和可持续性发展的日益重视,作为近十年来的新兴学科,绿色化学,逐渐引起化学工作者的关注。在这个研究领域中,我们一方面主要致力于对环境友好的反应介质 ( 如离子液体 ) 的开发;另一方面则寻找对环境和可持续性发展有益的新反应工艺。如用分子氧(空气中)来替代传统的无机氧化剂,如铬酸,高锰酸钾等,后者对环境和人类健康有极强的破坏作用。 
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【主要论著】

  • 近期代表性论文(Selected Publications)

    1.TingtingZheng,Junye Li, Shumiao Zhang, Benjing Xue,Hongjian Sun, Xiaoyan Li,*Olaf Fuhr andDieter Fenske, Selective CF and CH Activation of Fluoroarenes by Fe(PMe3)4 and CatalyticPerformance of Iron Hydride in Hydrosilylation of Carbonyl Compounds, Organometallics, 2016, DOI: 10.1021/acs.organomet.6b00546.

  • 2.Lin Wang,Hongjian Sun, Xiaoyan Li,* Olaf Fuhr, Dieter Fenske, The Selective Activationof C-F Bond with the Auxiliary of Strong Lewis Acid --- A Method to Change theActivation Preference of C-F and C-H bond,DaltonTrans., 2016, DOI: 10.1039/C6DT03235D.

  • 3. Benjing Xue,Hongjian Sun, YanWang, Tingting Zheng, Xiaoyan L*, Olaf Fuhr, Dieter Fenske, Efficientreductive dehydration of primary amides to nitriles catalyzed by hydridothiophenolato iron(II) complexes under hydrosilation conditions, Catalysis Communications, 2016, 86,148150.

  • 4. ShumiaoZhang, Xiaoyan Li, Hongjian Sun, * Olaf Fuhr, Dieter Fenske, Nickel(II)complexes of amine functionalized N-heterocyclic carbenes (NHCs), synthesis andcatalysis in Kumada coupling of aryl chlorides, J. Organomet.Chem., 2016,820,41-45.

  • 5. 孙宏建 李晓燕*,过渡金属氢化物在CO2活化和功能化反应中的应用, 有机化学,2016, DOI: 10.6023/cjoc201605037

  • 6. Lin Wang,Hongjian Sun,  Zhenyu Zuo, Xiaoyan Li,*,Weiqin Xu, Robert Langer,  Olaf Fuhr,Dieter Fenske , The Activation of CO2, CS2 and the Formic Acid DehydrogenationCatalyzed by Iron(II) Hydride Complexes, Eur.J.Inorg. Chem., 2016,10.1002/ejic.201600642

  • 7. Yaomin Shi, XiaoyanLi, Tingting Zheng, Benjing Xue, Shumiao Zhang, Hongjian Sun*, Olaf Fuhr,Dieter Fenske, Synthesis and Reactivity of Silyl Iron Hydride via Si-H BondActivation, Inorganica Chimica Acta, 2016,dx.doi.org.2016.10.017.

  • 8.Xiong, Zichang;Li, Xiaoyan; Zhang, Shumiao; Shi,Yaomin and Sun, Hongjian*, Synthesis andReactivity of NHeterocyclic PSiP Pincer Iron and Cobalt Complexesand Catalytic Application of Cobalt Hydride in Kumada Coupling Reactions, Organometallics, 35, 357−363, 2016.

  • 9. Qingfen Niu,Shumiao Zhang, Xiaoyan Li, Hongjian Sun,* Olaf Fuhr and Dieter Fenske, Synthesisand Characterization of Diorganocobalt Chlorides by Aliphatic Vinylic C–Cl BondActivation, Z. Anorg. Allg. Chem.,2016,642, 866-869.

  • 10.Yuan, Shuo;Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan*, Synthesis of fluorophenyl carbonylcobalt(I) complexes and decarbonylation of 2,4,5-trifluorobenzaldehydecatalyzed by CoMe(PMe3)4, Inorganica Chimica Acta, 43, 100–105, 2016.

  • 11.Wang, Lin;Sun, Hongjian; Li, Xiaoyan*, Imine Nitrogen Bridged Binuclear Nickel Complexesvia N−H Bond Activation: Synthesis, Characterization, Unexpected C,N-CouplingReaction, and Their Catalytic Application in Hydrosilylation of Aldehydes, Organometallics, 34, 5175−5182, 2015。

  • 12.Zhou,Hongwei; Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan*Synthesis and Reactivity ofa Hydrido CNC Pincer Cobalt(III) Complex and Its Application in Hydrosilylationof Aldehydes and Ketones, Organometallics,34, 1479−1486, 2015.

  • 13.Xue, Benjing;Sun, Hongjian; Li, Xiaoyan*, Syntheses and catalytic application of hydridoiron(II) complexes with [P,S]-chelating ligands in hydrosilylation of aldehydesand ketones, RSC Adv.,5, 52000-52006,2015.

  • 14.Zhang,Shumiao;, Li, Xiaoyan Li and Sun,Hongjian*, Selective amination of arylchlorides catalysed by Ni(PMe3)4, Dalton Trans., 44, 16224-16227,2015.

  • 15.Zhao,Hua;Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan*Synthesis and Characterization of Iron, Cobalt, andNickel [PNP] Pincer Amido Complexes by N–H Activation, Z. Anorg. Allg. Chem.641, (14),2435–2439,2015.

  • 16.赵华,孙宏建,王麟,李晓燕*,利用碳氢键活化合成钴的钳式配合物及其性质研究, , DOI: 10.6023/A15030190,2015.

  • 17.Peng, Zheng;Sun, Hongjian; Du, Aiqin; Li, Xiaoyan*Introduction of (2-CF3)Phenyl Group viaNickel-catalyzed C–Cl Bond Activation and Arylation, Z. Anorg. Allg. Chem., 641, (5), 838–84, 2015.

  • 18.Huang,Shaofeng, Zhao, Hua, Li,Xiaoyan, Wang, Lin and Sun, Hongjian,*,Synthesis of[POCOP]-pincer iron and cobalt complexes via Csp3–H activation and catalytic applicationof iron hydride in hydrosilylation reactions, Rsc Adv., 5, 15660-15667, 2015.

  • 19.Zhu, Gengyu,Wang, Lin, Sun,Hongjian, Li, Xiaoyan,* Formation of PCP pincer cobalt complexeswith cobalt acyclopropane moieties via double Csp 3–H bond activation, RscAdv., 5,19402-19408, 2015.

  • 20.Niu,Qingfen;Zhang,Xiaohan; Zhang,Shumiao; Li, Xiaoyan and Sun, Hongjian*, Activation ofvinylic carbon–chlorine bond by nickel complexes supported with phosphineligands, Qingfen Niu, Inorg.Chim. Acta., 426, 165-170,2015.

  • 21.Xu,Shilu, Li,Xiaoyan, Zhang Shumiao,Sun, Hongjian*, Synthesis and characterization of stabletripodal silyl ironand nickel Complexes, Inorg. Chim. Acta., 430, 161-167, 2015.

  • 22.Guo,Yingmian, Zhang, Xiaohan,Wang, Lin, Sun, Hongjian and Li, Xiaoyan,*,Synthesisof Dinuclear Nickel Complexes from Dimethyltris(trimethylphosphine)nickel(II)via N–H Bond Activation, Z. Anorg. Allg. Chem., 641, 669-672, 2015.

  • 23.Wang, Lin,Sun, Hongjian and Li,Xiaoyan,*Synthesis of Iron Hydrides via Selective C-F/C-HBond Activation in Fluoroaryl-imines and their Applications in CatalyticReduction Reactions, Eur.J. Inorg. Chem., 2732–2743, 2015.

  • 24.Zhou,Hongwei, Sun, Hongjian,Zheng, Tingting, Zhang, Shumiao, Li, Xiaoyan*, Synthesisof Vinyl Nickel and Nickelacyclopropane Complexes Containing a Chelate [P,Se]-ligand, Eur.J.Inorg. Chem., 3139–3145, 2015.

  • 25.Zhao,Hua,Sun, Hongjian and Li,Xiaoyan*, Synthesisand Catalytic Property of Iron PincerComplexes Generated byCsp3-H Activation, Organometallics 33,3535-3539,2014.

  • 26.Zuo, Zhenyu,Sun,Hongjian, Wang,Lin and Li,Xiaoyan*, Hydrosilylation of Aldehydes andKetones Catalyzed by Hydrido Iron Complexes Bearing Imine Ligands, DaltonTrans., 43,11716-11722, 2014.

  • 27. Zhu, Gengyu; Li, Xiaoyan; Xu, Guoqiang; Wang, Lin;Sun, Hongjian*,A new PC(sp3)P ligand and its coordination chemistry withlow-valent iron,cobalt and nickel complexes, Dalton Trans.,DOI:10.1039/C4DT00639A, 2014

  • 28. Sun, Yunqiang, Li, Xiaoyan; Sun, Hongjian*,Arylationof non-activatedC–Cl bond with Grignard reagents catalyzed by pincer[PCP]-nickel complexes, Inorg. Chim. Acta, 415, 95–97, 2014.

    29. Li, Junye; Li,Xiaoyan; Wang Lin; HuQingping*; Sun, Hongjian*, Selective C-Cl Bond Activationand CatalyticHydrodechlorination of Hexachlorobenzene by Cobalt and NickelComplexes withSodium Formate as Reducing Agent, DaltonTrans.,43,6660-6666, 2014.

    30. Lu, Yunqiang;Li, Xiaoyan; Wang, Lin; Sun,Hongjian*, C-O Bond Activation andSubsequent Decarbonylation ofEster Promoted by Fe(PMe3)4,Inorg. Chem. Comm.,41,51-53, 2014.

    31. Lu, Faguan;Sun, Hongjian; Du, Aiqin; Feng, Lei;Li, Xiaoyan*, Selective AlkylationandArylation of C−F Bond with Grignard Reagents,Org.Lett., 16,772-775,2014.

    32. Sun, Yunqiang;Sun, Hongjian; Jia, Jiong;Du Aiqin; Li, Xiaoyan*, Transition-Metal-FreeSynthesis of Fluorinated Arenesfrom Perfluorinated Arenes Coupled with GrignardReagents, Organometallics 33, 1079−1081, 2014.

    33. Niu,Qingfen ; Sun, Hongjian ; Wang, Lin Hu,Qingping* andLi, Xiaoyan*, Reactivityofmer-hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III) complex, DaltonTrans., 43, 4059–4066, 2014.

    34. Li,Junye;Zheng, Tingting; Sun, Hongjian; Xu, Wengang; Li, Xiaoyan*, Selective C-F/ C-HBond Activation of Fluoroarenes by Cobalt Complex supported withphosphineligands, Dalton Trans., 42, 5740-5748, 2013.

    35. Wu, Siquan;Li, Xiaoyan; Xiong, Zichang; Xu, Wengang; Lu, Yunqiang; andSun Hongjian*,Synthesis and Reactivity of Silyl Iron, Cobalt, and NickelComplexes Bearing a[PSiP]-Pincer Ligand via Si−H Bond Activation Organometallics 32, 3227-3237, 2013.

    36. Huang, Ning;Li, Xiaoyan; Sun, Hongjian*, Nickel–heterocumulenecomplexes stabilized bytrimethylphosphine: Synthesis, characterization andcatalytic application inorganozinc coupling with CS2, Inorg. Chim. Acta, 394,446–451, 2013.

    37. Xu, Wengwng;Sun, Hongjian; Xiong, Zichang; LiXiaoyan*, Acid-PromotedSelectiveCarbon−Fluorine Bond Activation and Functionalization ofHexafluoropropene byNickel Complexes Supported with Phosphine Ligands,Organometallics,32, 7122-7132, 2013.

    38. Niu, Qingfen;Sun, Hongjian; Li,Xiaoyan*; Klein, H.-F. and Flörke,Ulrich, Synthesis and CatalyticApplication in Hydrosilylation of theComplexmer-Hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III), Organometallics,32, 5235-5238, 2013.

    39. Li, Junye;Zheng, Tingting; Sun,Hongjian; Li, Xiaoyan*, Selectivelycatalytic hydrodefluorinationof perfluoroarenes by Co(PMe3)4with sodium formate asreducing agent and mechanism study,Dalton Trans., 42,13048-13053, 2013.

    40. Li, Junye; Li,Xiaoyan; Sun, Hongjian*, Synthesis and characterization ofnovel organonickeland organocobalt complexes via carbonechlorine bondactivation, J.  Organomet.Chem. 743,114-122, 2013.

    41. Li, Junye;Wang,Chenggen; Li, Xiaoyan and Sun, Hongjian*, C–Cl bond activationofortho-chlorinated benzamides by nickel and cobalt compounds supportedwithphosphine ligands, Dalton Trans., 41,8715-8722, 2012.

    42. Liu, Nazhen;Li, Xiaoyan; Xu,Xiaofeng; Wang, Zhiping; Sun, Hongjian*, Synthesis, structureand DFTstudy of dinuclear iron, cobalt and nickel complexeswithcyclopentadienyl-metal moieties. DaltonTrans., 40, 6886–6892,2011.

    43. Liu, Nazhen;Li, Xiaoyan; Sun, Hongjian*, Synthesis and properties ofnovel ortho-metalatedcobalt(I) andiron(II) complexes through Csp2-H bond activation ofdibenzylphenylphosphine. J. Organomet. Chem.,696, 2537-2542, 2011.

    44.Xu, Guoqiang;Li, Xiaoyan; Sun, Hongjian*, Nickel-catalyzedcross-coupling of primary alkylhalides with phenylethynyl- andtrimethylsilyethynyllithium reagents. J.Organomet. Chem.696, 3011-3014, 2011.

    45. Zhang, Chen;Li,Xiaoyan; Sun, Hongjian*, Palladium-catalyzedhydrodechlorination of arychlorides and its mechanism. Inorg. Chim. Acta, 365, 133-136, 2011.

    46. Wang,Chenggen; Sun,Hongjian; Hu, Qingping; Li, Xiaoyan*, Carbonylativeformation ofN-acetyl-2,6-difluorobenzamide through N-H bond activationof2,6-difluorobenzamide with Ni(II) complex supported with phosphine ligands. J.Organomet. Chem., 696, 2815-2819, 2011.

    47. Xu, Xiaofeng;Sun,Hongjian; Shi, Yujie; Jia, Jiong and Li, Xiaoyan *,Imine-assisted C–F bondactivation by electron-rich iron complexessupported by trimethylphosphine.DaltonTrans., 40, 7866–7872, 2011.






【科研项目】

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    2013.01--2016.12  铁、钴和镍配合物对Si-H键的活化及功能化作用,国家自然科学基金(批准号:21272138)。

    2011.01--2013.12  铁、钴和镍的钳式配合物在碳碳和碳杂原子偶联反应中的催化作用,国家自然科学基金(批准号:21072113)。

    2009.01--2011.12  低价态铁、钴和镍有机膦配合物对C-Cl键的活化及功能化反应研究,国家自然科学基金(批准号:20872080)。

    2004.01--2006.12  离子型过渡金属双亚胺配合物的合成及其在离子液体中的催化作用,国家自然科学基金(批准号:20372042)。

    2011.01--2013.12  钳式配合物在碳碳偶联反应中的催化作用,山东省自然科学基金重点项目。2007.01--2008.12 环境友好的芳香族氯化物的催化脱氯研究,山东省自然科学基金。

    2001.01--2005.12  环境友好的有机催化反应,山东省科技开发项目。

     

     

【科研成果】

  • 已发表学术论文160余篇 
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【所获专利】

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【联合培养情况】

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【拟招收研究生情况】

  •  每年计划招收2名硕士研究生,1-2名博士研究生。
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