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导师风采

【个人简介】

姓 名:  孙德军
性 别:  男
出生日期: 1965-07-16

学 历:  博士研究生

职 称:  教授 ( 博导 [聘任于2002年])
学术身份行政职务:  胶化所 所长

研究类别:  物理化学

工作单位:  胶体与界面化学研究所

                 胶体与界面化学教育部重点实验室

电 话:  0531-88364749

传 真:  0531-88365437

E-mail:  djsun@sdu.edu.cn

地 址:  山东省济南市山大南路27号山东大学中心校区

【学习及工作经历】

 

1986年山东大学化学系获学士学位,1989年获硕士学位后留校任教,后获物理化学专业博士学位。

【主讲课程】

 胶体体系相行为、分散体系流变学、表面活性剂应用化学

【研究领域和兴趣】

 体相与界面无机纳米粒子的自组装;表面活性剂、纳米粒子和聚合物协同稳定的乳液;油田胶体化学

 

1.  LDH (layered double hydroxide)片状纳米粒子-水分散体系

 

     通过水分散体系中LDH纳米粒子间相互作用的调控,使体系有序-无序相转变和粒子由体相至界面的迁移得以实现。继LDH胶体体系中形成向列相(Chem. Mater. 2003, 15, 3240)之后,同步辐射小角X 射线散射等手段又证实了特定LDH胶体体系中层状相的存在;两亲共聚物使LDH悬浮体耐温、耐盐和剪切稳定性极大地提高;加盐可调控LDH纳米粒子至油水界面,从而制得稳定o/w乳液。

 

2.  乳液制备与应用

 

    用表面活性剂、疏水改性聚合物以及合成锂皂石、LDH片状纳米粒子等制备了石蜡乳液,室内研究以及胜利油田、渤海BZ 25-1(中海油天津分公司)、华北油田、中石化西北分公司(新疆)、滇黔桂石油勘探局临盘钻探公司等油田区块累计600多吨、上百口井的现场试验表明,乳液具有优异的防塌、润滑和保护油气层等作用。

【主要论著】

pH Switchable Emulsions Based on Dynamic Covalent Surfactants.Langmuir,33(12),3040-3046,2017

 

High temperature stable W/O emulsions prepared with in-situ hydrophobically modified rodlike sepiolite. Journal of Colloid and Interface Science, 493:378-384, 2017
 
Highly effective emulsification/demulsification with a CO2-switchable superamphiphile. Journal of Colloid and Interface Science , 480:198-204,2016
 

Preparation of CO2 -responsive emulsions with switchable hydrophobic tertiary amine. Colloids and Surfaces A, 502:107-113,2016

 

Formation of nanoemulsion with long chain oil by W/O microemulsion dilution method. Colloids and Surfaces A,497:101-108, 2016

 

An efficient hydrogen evolution catalyst composed of palladium phosphorous sulphide (PdP∼0.33S∼1.67) and twin nanocrystal Zn0.5Cd0.5S solid solution with both homo- and hetero-junctions. Energy & Environmental Science, 10, 225--235, 2016

 

Adsorption behavior and mechanism of chlorophenols onto organoclays in aqueous solution. Colloids and Surfaces A, 484:118-129, 2015

 

Formation of Concentrated Nanoemulsion by W/O Microemulsion Dilution Method: Biodiesel, Tween 80, and Water System. ACS Sustainable Chemistry and Engineering, 3(12) ,3299-3306, 2015

 

Influence of emulsification process on the properties of pickering emulsions stabilized by layered double hydroxide particles. Langmuir, 31(16):4619-26, 2015

 

Effect of cetyltrimethylammonium bromide addition on the emulsions stabilized by montmorillonite. Colloid and Polymer Science, 292(2):441-447, 2014

 

Preparation of highly stable concentrated W/O nanoemulsions by PIC method. Colloids and Surfaces A,447(447) :97-102, 2014

 

Colloidal properties of montmorillonite suspensions modified with polyetheramine. Colloids and Surfaces A,457(1):8-15 , 2014  

 

 Ca2+ Ion Responsive Pickering Emulsions Stabilized by PSSMA Nanoaggregates. Langmuir, 29(47):14421-14428, 2013

 

Effect of polyisobutylenesuccinimide onlow-temperature rheology and dispersibility of clay particles in mineral oil. Colloids and Surfaces A, 431:133-141, 2013

 

Phase Inversion of Emulsions Containing a LipophilicSurfactant Induced by Clay Concentration. Langmuir, 29(12): 3889-3894, 2013

 

Roles of methyl orange in preparation of emulsionsstabilized by layered double hydroxide particles. Colloids and Surfaces A, 421:173-180, 2013

 

Aqueous Dispersions of MgAl Double Hydroxide Particlesof Different Forms and Stabilized Pickering Emulsions. Chemical Journal of Chinese Universities-Chinese, 34(2):386-393, 2013

 

Enhanced Ca2+ binding with sulfonic acid type polymersat increased temperatures. Colloids and Surfaces  A, 417:256-263, 2013

 

Dispersion stability of organoclay in octane improvedby adding nonionic surfactants. Colloids and Surfaces  A, 415:180-186, 2012

 

Highly Stable Concentrated Nanoemulsions by the PhaseInversion Composition Method at Elevated Temperature.  Langmuir, 28(41):14547-14552, 2012

 

Double Inversion of Emulsions Induced by SaltConcentration. Langmuir, 28(17):6769-6775, 2012

 

Oil-in-water emulsions stabilized by Laponiteparticles modified with short-chain aliphatic amines. Colloids and  Surfaces A, 400:44-51, 2012

 

Preparation of positively charged oil/waternano-emulsions with a sub-PIT method. Journal of Colloid and Interface Science, 361(2):565-572, 2011

 

In situ formed Mg(OH)(2) nanoparticles aspH-switchable stabilizers for emulsions. Journal of Colloid and Interface Science, 359(1):155-162, 2011

 

Temperature induced formation of particle coatednon-spherical droplets. Journal of Colloid and Interface Science,  359(1):171-178, 2011

 

Effect of poly(oxypropylene)diamine adsorption onhydration and dispersion of montmorillonite particles in aqueous solution.  Colloids and Surfaces A, 381(1-3):41-47, 2011

 

O/W nano-emulsions with tunable PIT induced byinorganic salts. Colloids and Surfaces A, 375(1-3):102-108, 2011

 

Double Flocculation in Aqueous Dispersion of Layered DoubleHydroxide Particles Induced by Sodium Polyacylate. Chemical Journal of Chinese Universities-Chinese, 31(10):2030-2035, 2010

 

Rearrangement of layered double hydroxide nanoplatelets during hollow colloidosome preparation. Journal of Colloid and Interface Science, 345(2): 302-306, 2010

 

Pickering Emulsions Stabilized by a Lipophilic Surfactant and Hydrophilic Platelike Particles. Langmuir, 26(8), 5397-5404, 2010

 

Formation and properties of paraffin wax submicron emulsions prepared by the emulsion inversion point method. Colloids and Surfaces A,356(1-3), 71-77, 2010

 

Foams stabilized by Laponite nanoparticles and alkylammonium bromides with different alkyl chain lengths. Colloids and Surfaces A, 355(1-3), 151-157, 2010

 

Aqueous foam stabilized by plate-like particles in the presence of sodium butyrate,. Journal of Colloid and Interface Science, 343(1): 87-93, 2010

 

Synergistic stabilization of emulsions by poly(oxypropylene)diamine and Laponite particles. Colloids and Surfaces A, 353(2-3), 117-124, 2010

 

Aqueous foam stabilized by hydrophobically modified silica particles and liquid paraffin droplets. Colloids and Surfaces A,353(2-3), 181-188, 2010

 

Aqueous foam stabilized by hydrophobically modified cellulose and alkyl polyoxyethyl sulfate complex in the presence and absence of electrolytes. Colloids and Surfaces A,345(1-3), 58-64, 2009

 

The phase behavior of mixtures of positively charged colloidal platelets and nonadsorbing polymer. Langmuir,25 (11): 6349-6356, 2009

 

Dispersion control and nematic ordering of Ni/Al layered double hydroxide suspensions. Journal of Solid State Chemistry,182 (6): 1462-1467, 2009

 

Pickering emulsions stabilized by paraffin wax and Laponite clay particles. Journal of Colloid and Interface Science, 336(1): 314-321, 2009

 

Aqueous foams stabilized by hexylamine-modified Laponite particles. Colloids and Surfaces A, 338(1-3): 40-46, 2009

 

Double phase inversion of emulsions containing LDHs particles induced by adsorption of sodium dodecyl sulfate. Langmuir,  24 (18): 10054–10061, 2008

 

Aqueous foams stabilized with particles and nonionic surfactants. Colloids and Surfaces A, 324(1-3):1-8, 2008

 

Aqueous foams stabilized by Laponite and CTAB. Colloids and Surfaces A, 317(1-3):406-413, 2008

 

Study of assembly of arachidic acid/LDHs hybrid films containing photoactive dyes. Journal of Colloid and Interface

 Science, 318(2):337-347, 2008

 

Phase behavior of aqueous suspensions of Mg2Al Layered Double Hydroxide: the competition among nematic ordering, sedimentation and gelation. Langmuir,23(10): 5331-5337, 2007

 

Multiphase coexistence in colloidal dispersions of positively charged layered double hydroxides. Colloids and Surfaces A,301(1-3):106-112, 2007

 

Synergistic effect of silica nanoparticle and cetyltrimethyl ammonium bromide on the stabilization of O/W emulsions. Colloid and Surface A,302(1-3):126-135, 2007

 

Oil-in-water emulsions stabilized by hydrophobically modified hydroxyethyl cellulose: adsorption and thickening effect. Journal of Colloid and Interface Science,311(1):228-236, 2007

 

Synthesis of bilayer oleic acid coated Fe3O4 nanoparticles and their application in pH-responsive Pickering emulsions. Journal of Colloid and Interface Science,310(1):260-269, 2007

 

Effect of dispersion pH on the formation and stability of Pickering emulsions stabilized by layered double hydroxides particles. Journal of Colloid and Interface Science, 306 (2): 285-295, 2007

 

Formation and stability of paraffin oil-in-water nano-emulsions prepared by the emulsion inversion point method. Journal of Colloid and Interface Science, 303 (2): 557-563, 2006

 

Pickering emulsions stabilized solely by layered double hydroxides particles: The effect of salt on emulsion formation and stability. Journal of Colloid and Interface Science, 302 (1): 159-169, 2006

 

The effect of block copolymer EPE1100 on the colloidal stability of Mg–Al LDH dispersions. Journal of Colloid and

Interface Science, 289(2): 410-418, 2005

 

Lamellar phase in colloidal suspensions of positively charged LDHs platelets. Soft Matter, 1 (6): 428-430, 2005

 

Effect of additives on the cloud points of two tri-block copolymers in aqueous solution. Colloid and Surface A, 237 (1-3): 1-6, 2004

 

Swelling inhibition by polyglycols in montmorillonite dispersions. J. Disper. Sci. Technol., 25 (1): 63-66, 2004

 

Liquid-crystalline phases of colloidal dispersions of Layered Double Hydroxides. Chemistry of Materials,15 (17):

3240-3241, 2003

 

Synthesis and characterization of polyoxyethylene sulfate intercalated Mg-Al-Nitrate Layered Double Hydroxide. Langmuir, 19 (14):5570-5574, 2003

 


LDH胶体分散体系的工作被PNAS, Phys. Rev. Lett.,J. Am. Chem. Soc.,Curr. Opin. Colloid Inter. Sci.,J. Phys. Chem. B.,Langmuir,J. Colloid Inter.  Sci.,Pure Appl. Chem.,  Nanotechnology等引用。
 

【科研项目】

1. 低品石油资源开发利用中界面分子相互作用与聚集的物理化学基础,国家自然基金委,起止时间:2014-2018

 

2. 水平井产油潜力段保护与伤害修复技术研究,中石化,起止时间:2015-2018

 

3. MO-DRILL体系构建机理研究,中海油,起止时间:2015-2016

 

4. 微乳液在钻完井液中的应用研究,中海油,起止时间:2013-2014


5.  基于低能纳米乳化石蜡的环保型钻完井液在低渗油田的应用研究,陕西延长石油,起止时间:2010-2012

 

6.  电荷可控、微纳米尺度固体石蜡软微粒形成的“自封堵”多功能钻井液技术,国家863计划,起止时间:2010-2012

 

7.  基于低能乳化石蜡的新型环保钻井完井液技术,国家863计划,起止时间:2006-2008

 

8.  环保型悬乳液体系的研究与应用, 中石化,起止时间:2005-2007

【科研成果】

1.  多元金属氢氧化物超细粉制备及应用研究,国家科技部,国家科技进步二等奖,2001;

 

2.  多元金属氢氧化物超细粉制备及应用研究,山东省科技厅,科技进步一等奖,2000;

 

3.  MMH正电溶胶,教育部,科技进步二等奖,1999

【所获专利】

1. 一种采用开关型溶剂处理含油钻屑的方法,专利号:ZL201510655759.8,授权公告日:2016.10.26

 

2. 一种微乳液型油污清洗剂及其制备方法,专利号:ZL201310475353.2,授权公告日:2016.01.13

 

3. 一种通过原位形成有机土增稠生物柴油的方法,专利号:ZL201310475354.7,授权公告日:2016.01.13

 

4. 一种适用于高温高盐环境的油基泥浆冲洗液及其制备方法,专利号:ZL201310548607.9,授权公告日:2015.12.09

 

5. 一种原位形成纳米乳液的微乳液及其制备方法,专利号:ZL201210205140.3,授权公告日:2014.10.29

 

6. 一种钻井液高温高盐稳定剂的制备方法及其应用,专利号:ZL201010556332.X,授权公告日:2013.04.03

 

7. 钻井液用梳型聚合物降滤失剂及其制备方法,专利号:ZL201010254507.1,授权公告日:2013.01.02

 

8. 一种正电纳米乳液的低能制备方法,专利号:ZL200910231495.8,授权公告日:2011.11.30

 

9. 一种钻井液用润滑剂及其制备方法,专利号:ZL200810238612.9,授权公告日:2010.12.29

 

10.一种带正电石蜡纳米乳液及其制备方法,专利号:ZL200710113845.1,授权公告日:2010.10.13

 

11.一种多功能钻井液添加剂及其制备方法与应用,专利号:ZL200510042592.4,授权公告日:2007.02.28

 

12.一种颗粒稳定乳液体系及其制备方法与作为钻井液润滑剂的应用,专利号:ZL200510043869.5,授权公告日:2007.11.14

【联合培养情况】

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【拟招收研究生情况】

拟招收学术型硕士及专业硕士各1-2名,博士1-2名。

 

欢迎具有分散体系、油田胶体化学基础或工作背景的人员报考。

 

培养的硕/博士生适合在高校、科研院所及企业研发部门等从事工作。

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